Correlation of Electrons in a Narrow s Band

Martin C. Gutzwiller
Phys. Rev. 137, A1726 – Published 15 March 1965
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Abstract

The ground-state wave function for the electrons in a narrow s band is investigated for arbitrary density of electrons and arbitrary strength of interaction. An approximation is proposed which limits all the calculations to counting certain types of configurations and attaching the proper weights. The expectation values of the one-particle and two-particle density matrix are computed for the ferromagnetic and for the non-ferromagnetic case. The ground-state energy is obtained under the assumption that only the intra-atomic Coulomb interaction is of importance. Ferromagnetism is found to occur if the density of states is large at the band edges rather than in the center, and if the intra-atomic Coulomb repulsion is sufficiently strong. The relation of this approximation to certain exact results for one-dimensional models is discussed.

  • Received 22 October 1964

DOI:https://doi.org/10.1103/PhysRev.137.A1726

©1965 American Physical Society

Authors & Affiliations

Martin C. Gutzwiller

  • IBM Watson Laboratory, Columbia University, New York, New York

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Issue

Vol. 137, Iss. 6A — March 1965

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