Rayleigh scattering in a liquid far from thermal equilibrium

P. N. Segrè, R. W. Gammon, J. V. Sengers, and B. M. Law
Phys. Rev. A 45, 714 – Published 1 January 1992
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Abstract

We report the results of Rayleigh-scattering experiments in liquid toulene that is subjected to a stationary temperature gradient, but which otherwise is kept in a quiescent state. The measurements were made with temperature gradients up to 224 K/cm and scattering angles down to 0.45°. They probe fluctuations with wavelengths up to 40 μm and demonstrate the presence of long-range fluctuations in a nonequilibrium liquid. The strength of the observed nonequilibrium heat-mode and viscous-mode fluctuations varies with the square of the temperature gradient and with the fourth power of the wavelength of the fluctuations, in agreement with the behavior predicted by fluctuating hydrodynamics.

  • Received 19 August 1991

DOI:https://doi.org/10.1103/PhysRevA.45.714

©1992 American Physical Society

Authors & Affiliations

P. N. Segrè, R. W. Gammon, and J. V. Sengers

  • Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742

B. M. Law

  • Department of Physics, Kansas State University, Manhattan, Kansas 66506

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Issue

Vol. 45, Iss. 2 — January 1992

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