From dynamics to thermodynamics: Linear response and statistical mechanics

Marco Bianucci, Riccardo Mannella, Bruce J. West, and Paolo Grigolini
Phys. Rev. E 51, 3002 – Published 1 April 1995
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Abstract

We illustrate a dynamic approach to statistical mechanics based on a procedure which reverses the standard approach to the Fokker-Planck equation (FPE). Rather than using statistical mechanics, derived from thermodynamics along the lines pioneered by Boltzmann [L. Boltzmann, Wiss. Ber. 58, 517 (1868)], we derive a FPE for a set of variables of interest interacting with a booster, i.e., a dynamical system mimicking the action of an ideal thermostat with no need of ad hoc statistical assumptions. We derive a mechanical expression for the temperature of the system of interest, which is proven to be a generalization of the one proposed by Boltzmann; in the case of boosters with a limited number of degrees of freedom, it is shown that our definition depends also on dynamic properties, which are not accounted for by the ‘‘standard’’ approach.

  • Received 12 October 1994

DOI:https://doi.org/10.1103/PhysRevE.51.3002

©1995 American Physical Society

Authors & Affiliations

Marco Bianucci

  • Dipartimento di Fisica dell’Università di Pisa, Piazza Torricelli 2, 56100 Pisa, Italy
  • Dipartimento di Fisica dell’Università di Pavia, Via Bassi 6, 27100 Pavia, Italy

Riccardo Mannella

  • Dipartimento di Fisica dell’Università di Pisa, Piazza Torricelli 2, 56100 Pisa, Italy

Bruce J. West

  • Department of Physics, University of North Texas, P.O. Box 5368, Denton, Texas 76203

Paolo Grigolini

  • Dipartimento di Fisica dell’Università di Pisa, Piazza Torricelli 2, 56100 Pisa, Italy
  • Department of Physics, University of North Texas, P.O. Box 5368, Denton, Texas 76203
  • Istituto di Biofisica del Consiglio Nazionale delle Ricerche, Via San Lorenzo 28, 56127 Pisa, Italy

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Issue

Vol. 51, Iss. 4 — April 1995

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