Coexistence of multiple phases in finite systems

Ralph E. Kunz and R. Stephen Berry
Phys. Rev. Lett. 71, 3987 – Published 13 December 1993
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Abstract

Dynamic coexistence of several phaselike forms, a solid, microcrytalline phase, a homogeneously melted phase, and phases exhibiting a solid core and a melted surface, is found in isothermal molecular dynamics simulations of magic-number rare gas clusters. We present a mean-field model showing that the observed behavior is possible if (a) the core and surface both undergo finite-system analogs of first-order transitions with overlapping coexistence regions and (b) the mode-softening defects of the core exhibit an attractive interaction with the vacancy-floater pairs on the surface.

  • Received 13 August 1993

DOI:https://doi.org/10.1103/PhysRevLett.71.3987

©1993 American Physical Society

Authors & Affiliations

Ralph E. Kunz and R. Stephen Berry

  • Department of Chemistry and the James Franck Institute, The University of Chicago, Chicago, Illinois 60637

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Vol. 71, Iss. 24 — 13 December 1993

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