Liquid Crystal Formation in Suspensions of Hard Rodlike Colloidal Particles: Direct Observation of Particle Arrangement and Self-Ordering Behavior

Hideatsu Maeda and Yoshiko Maeda
Phys. Rev. Lett. 90, 018303 – Published 10 January 2003

Abstract

We successfully prepared monodisperse, hard rodlike colloidal particles with a wide range of length-to-width ratios (L/W). In their suspensions liquid crystals, or nematic (N) and smectic (Sm) phases, spontaneously appeared. The size of the particles made it possible to directly observe their arrangement and dynamics with an optical microscope. The phase behavior observed exhibited an I (isotropic)-Sm transition for L/W=3.58.0 and INSm transitions for L/W=1035. In pre-Sm transition regions, lateral clustering of the particles and subsequent layering of the clusters were observed exactly.

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  • Received 19 July 2002

DOI:https://doi.org/10.1103/PhysRevLett.90.018303

©2003 American Physical Society

Authors & Affiliations

Hideatsu Maeda1 and Yoshiko Maeda2

  • 1National Institute of Advanced Science and Technology (AIST), Institute for Biological Resources and Functions, AIST Tsukuba Central 6, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8566 Japan
  • 2The University of Tsukuba, 1-1-1 Tennodai, Ibaraki, 305-8574 Japan

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Vol. 90, Iss. 1 — 10 January 2003

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