Abstract
We successfully prepared monodisperse, hard rodlike colloidal particles with a wide range of length-to-width ratios (). In their suspensions liquid crystals, or nematic () and smectic (Sm) phases, spontaneously appeared. The size of the particles made it possible to directly observe their arrangement and dynamics with an optical microscope. The phase behavior observed exhibited an (isotropic)-Sm transition for and transitions for . In pre-Sm transition regions, lateral clustering of the particles and subsequent layering of the clusters were observed exactly.
- Received 19 July 2002
DOI:https://doi.org/10.1103/PhysRevLett.90.018303
©2003 American Physical Society